Helix-Coil Transition Theory: from biophysics to biochemistry via probability ~ Lauraine Dalton - SlideServe
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SOLVED:Polypeptides are polymers of amino acids. Suppose that a long polypeptide chain can undergo a transition from a helical conformation to a random coil. Consider a mechanism for a helix-coil transition that begins in the middle of the chain: h h h h …⇄ h c h h … h c h h …⇄ c c c c … in which h and c label, respectively, an amino acid in a helical or coil part of the chain. The first conversion from h to c, also called a nucleation step, is relatively slow, so neither step may be
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